Wear trainers not sling backs. Molten solder and your tootsie don't go well together.
I turn the printed circuit board component side down and wave a hot air gun over the flip side, whilst tapping the board against the edge of work bench. The result is usually a cascade of components (and blobs of molten solder).
Very therapeutic. When I'm stuck trying to work out how to do something, when everything I have tried has failed miserably, I deconstruct something electronic. No, I keep well away from psychiatrists.
You (I anticipate) won't be doing this 9 hours a day, 7 days a week - most of the nasties are long term exposure ones, so a one-off should be fine. If anything ever irritates your eyes or throat, get out of there and ventilate the place.