With soldering you want to maximize heat transfer at all times so flat surfaces (chisel tip for example) are usually ideal. If you want to remove solder from a hole in a PCB you’re better off with a round tip as that has the most contact area then. It will make it easier to use a solder sucker in that case for example. Personally I have the chisel tip on 90% of the time and might be willing to switch to the large flat one.